Disc: 1
1. Down to the Wire 2:28
* Previously unreleased (1967); performed with Buffalo Springfield members Stephen Stills and Richie Furay along with Dr. John; planned for inclusion on the unreleased album Stampede
2. Burned 2:15
* Performed by Buffalo Springfield; appears on the album Buffalo Springfield (1966)
3. Mr. Soul 2:48
* Performed by Buffalo Springfield; recorded live in the studio in New York City, New York, with guitar overdubs added subsequently; appears on the album Buffalo Springfield Again (1967)
4. Broken Arrow 6:11
* Performed by Buffalo Springfield; appears on the album Buffalo Springfield Again
5. Expecting to Fly 3:45
* Appears on the album Buffalo Springfield Again but no band member other than Neil Young appears on the track
6. Sugar Mountain 5:43
* Recorded live in concert on November 10, 1968 at the Canterbury House, Ann Arbor, Michigan; released as the B-side to "The Loner", February 21, 1969
7. I Am a Child 2:17
* Appears on the Buffalo Springfield album Last Time Around (1968) but features no members of the band other than Neil Young and drummer Dewey Martin
8. The Loner 3:50
* Appears on the album Neil Young (1968)
9. The Old Laughing Lady 5:38
* Appears on the album Neil Young
10. Cinnamon Girl 2:59
* Performed by Neil Young & Crazy Horse; appears on the album Everybody Knows This Is Nowhere (1969)
11. Down by the River 9:00
* Performed by Neil Young & Crazy Horse; appears on the album Everybody Knows This Is Nowhere
12. Cowgirl in the Sand 10:01
* Performed by Neil Young & Crazy Horse; appears on the album Everybody Knows This Is Nowhere
13. I Believe in You 3:27
* Performed by Neil Young & Crazy Horse; appears on the album After the Gold Rush (1970)
14. After the Gold Rush 3:45
* Appears on the album After the Gold Rush
15. Southern Man 5:31
* Appears on the album After the Gold Rush
16. Helpless 3:34
* Performed by Crosby, Stills, Nash & Young; appears on the album Déj? Vu (1970)

Disc: 2
1. Ohio 2:56
* Performed by Crosby, Stills, Nash & Young; released as a single, June 1970 and later appeared on So Far, 1974
2. Soldier 2:28
* Edited version originally from the album Journey Through the Past (1972)
3. Old Man 3:21
* Appears on the album Harvest (1972)
4. A Man Needs a Maid 3:58
* Appears on the album Harvest
5. Harvest 3:08
* Appears on the album Harvest
6. Heart of Gold 3:06
* Appears on the album Harvest
7. Star of Bethlehem 2:46
* Appears on the album American Stars 'n Bars (1977); originally recorded in November 1974
8. The Needle and the Damage Done 2:02
* Recorded live in concert on January 30, 1971 at the Royce Hall, University of California, Westwood, Los Angeles, California; appears on the album Harvest
9. Tonight's the Night (Part 1) 4:41
* Appears on the album Tonight's the Night (1975); originally recorded in 1973
10. Tired Eyes 4:33
* Appears on the album Tonight's the Night
11. Walk On 2:40
* Appears on the album On the Beach (1974)
12. For the Turnstiles 3:01
* Appears on the album On the Beach
13. Winterlong 3:05
* Previously unreleased; appeared on certain acetate pressings of Tonight's The Night
14. Deep Forbidden Lake 3:39
* Previously unreleased
15. Like a Hurricane 8:16
* Performed by Neil Young & Crazy Horse; previously unreleased (but originally recorded in November 1975); different lead vocal dub from version on American Stars 'n Bars (Regular version on 1990 reissue CD)
16. Love Is a Rose 2:16
* Previously unreleased
17. Cortez the Killer 7:29
* Performed by Neil Young & Crazy Horse; appears on the album Zuma (1975)
18. Campaigner 3:30
* Previously unreleased
19. Long May You Run 3:48
* Performed by Crosby, Stills, Nash & Young; previously unreleased; original mix (without Crosby and Nash) appears on the Stills-Young Band album Long May You Run (1976)